Definitely Depends
I would not doubt that more charity head offices in Canada are based in Toronto, it is a much bigger city and certainly contains the head offices of more charities in my sector (ex: greenpeace, wwf). That being said, Vancouver does have offices of both those companies, and it would likely be the same in your field (head office in Toronto but quite possibly an office in Vancouver as well). I would think you would want to secure a job first though before moving to either city?!
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